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Beilstein J. Org. Chem. 2017, 13, 639–643, doi:10.3762/bjoc.13.62
Graphical Abstract
Scheme 1: Examples of metal-catalyzed transformations of 1,11-dien-6-ynes.
Scheme 2: Cobalt-catalyzed cycloisomerizations of 1,11-dien-6-ynes.
Scheme 3: Possible mechanism for formation of the compounds 2–5.
Scheme 4: Cycloisomerization of the substituted dienyne 1c.
Figure 1: The substituted 1,11-dien-6-ynes that did not undergo cycloisomerization in the presence of the cob...